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Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-yl­methyl­idene)ethanamine-[kappa]3N,N',N'']manganese(II) monohydrate

In the title complex, [MnCl2(C13H13N3)]·H2O, the MnII atom is in a distorted square-pyramidal environment, with an Addison [tau] parameter of 0.037. The coordination geometry is defined by three N-atom donors from the tridentate 2-(pyridin-2-yl)-N-(pyridin-2-yl­methyl­idene)ethanamine ligand and two terminal Cl atoms. Although the H atoms of the lattice water molecule were not located, O...O distances of 3.103 (7) Å and O...Cl distances of 3.240 (3) and 3.482 (4) Å suggest that hydrogen bonding is responsible for the stabilization of the crystal packing.

Auteur(s) : D. Tinguiano, I. E. Thiam, M. Dieng, M. Gaye and P. Retailleau
Pages : M1250
Année de publication : 2012
Revue : Acta Crystallographica E
N° de volume : E68
Type : Article
Mise en ligne par : GAYE Mohamed Lamine