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{2-[(2-Acetyl­hydrazin-1-yl­idene)methyl-[kappa]2N1,O]-6-methoxy­phenolato-[kappa]O1}(nitrato-[kappa]O)copper(II) monohydrate

In the title complex, [Cu(C10H11N2O3)(NO3)]·H2O, prepared from the Schiff base N'-(3-meth­oxy-2-oxidobenzyl­idene)­acetohydrazide, the CuII atom is coordinated by two O atoms and one N atom from the ligand and one O atom from a nitrate group in a distorted square-planar geometry. The CuII atom has a weak inter­action with another O atom of the nitrate group. The two O atoms of the tridentate Schiff base ligand are in a trans arrangement. O-H...O and N-H...O hydrogen bonds involving the uncoordinated water mol­ecule are observed.


Auteur(s) : I. E. Thiam, P. Retailleau, A. Navaza and M. Gaye
Pages : m136
Année de publication : 2010
Revue : Acta Crystallographica E
N° de volume : E66
Type : Article
Mise en ligne par : GAYE Mohamed Lamine