In the title compound, [Ni2Cl2(C20H18N4)(H2O)4]Cl2·2C2H6O, the coordination environment of each Ni2+ ion is distorted octahedral formed by two N atoms from the Schiff base ligand, two O atoms from water molecules and two chloride anions acting as [mu]2 bridges between the metal ions. The coordinated water molecules are linked to the uncoordinated ethanol molecules and chloride anions by O-H...O and O-H...Cl hydrogen bonds, although the assignment of some of these is tentative. A weak intermolecular O-H...N interaction within the ligand is also observed.
Auteur(s) : E. I. Thiam, A. H. Barry, A. Navaza, P. Retailleau, M. Gaye and A. S. Sall
Pages : m1014
Année de publication : 1900
Revue : Acta Crystallographica E
N° de volume : E65
Type : Article
Mise en ligne par : GAYE Mohamed Lamine