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Crystal Structure and Spectroscopic Properties of [Fe(HL)2(NCS)2 (HL = 2-methoxy-6- ((phenylimino)methyl)phenol)

In the crystal structure of the title compound, [Fe(NCS)2(HL)2] (HL is 2-methoxy-6- ((phenylimino)methyl)phenol), the six-coordinated Fe(II) cation is bonded with two O-phenolate, two O-ether and two N-thiocyanate anions. In the complex, the ligand molecule acts as zwitterion. The complex 1 is characterized by elemental analysis, conductance measurement, room temperature magnetic susceptibility measurement and IR spectroscopic study. The complex 1 crystallizes in the monoclinic sp. gr. P21/n, Z = 4. In the crystal, the FeII cation is in a N2O4 core and is situated in a distorted octahedral environment. Furthermore, intermolecular hydrogen bonds link the molecules developing a 2D network parallel to ab plan.


Auteur(s) : Haba Pokpa, Mouhamadou Moustapha Sow, Ibrahima Elhadji Thiam, Mamour Sarr, Pascal Retailleau and Mohamed Gaye
Pages : 1-7
Année de publication : 2021
Revue : IOSR Journal of Applied Chemistry (IOSR-JAC)
N° de volume : 14(3)
Type : Article
Mise en ligne par : GAYE Mohamed Lamine