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Synthesis, Spectroscopic Studies and Crystal Structures of N, N’-bis (4-methoxybenzylidene) Ethylenediamine and an Its New Cadmium (II) Complex.

Schiff base (L) ligand is prepared via condensation of P-Anisaldehyde and ethylene diamine in 2:1 ratio in ethanol. A new complex is prepared by reacting this ligand with metallic salt CdI2. The structure of the two derivatives are confirmed using various spectroscopie techniques: C, H, N analyses, IR, UV-visible and X-ray diffraction. The IR spectrums of ligand and complex show respectively intense peaks at 1629 cm-' and 1639cm-' indicating the presence of azomethine group (N=C). The crystal structure of the ligand belongs respectively to monoclinic, space group P21/n. In the crystal packing of the ligand, molecules are linked by a pair of methyl-C-H... O(methoxy) interactions, forming to an infinite one-dimensional chain. The structural characterization of the complex reveals that it crystallizes in an orthorhombic system P with as space group Pbca with a=14.8704 A; b=12.9618 A; c=22.4416 A. The crystal structure of the monomer complex shows a distorted tetrahedral geometry. The Cd" center is coordinated by the bidentate schiff base ligand via the two imine groups (N-donor) and the two chlorine atoms. Non-classical intermolecular H-bonds of the type benzene-C-H... O (methoxy) exist and link the monomeric complex, forming one dimensional chains.


Auteur(s) : Ndioléne, Tidiane Diop, Mouhamadou Sembène Boye, Thierry Maris et Aminata Diassé-Sarr
Pages : 30-35
Année de publication : 2020
Revue : American journal of Heterocyclic Chemistry (AJHC).
N° de volume : 6
Type : Article
Mise en ligne par : BOYE Mouhamadou Sembène