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The synthesis and characterization of poly[dichloridotri(1,3-thiazolidine-2-thione)cadmium(II)], [CdCl2(C3H5NS2)3]n, prepared from CdCl2·H2O and C3H5NS2 (tzdSH) in a 1:3 ratio, are described. The CdII cation is coordinated by three 1,3-thiazolidine-2-thione molecules and three Cl? anions in a distorted octahedral environment. The Cd metal centres are connected via Cl? ligands, creating polymeric chains running along the a-axis direction. The conformation of the chains is stabilized by N—H?Cl hydrogen bonds.

Auteur(s) : A. Diop, T. Diop, A. B. Kama, C. A. K. Diop and N. Tumanov
Année de publication : 2020
Revue : International Union of Crystallography
N° de volume : Volume 5| Part 10| October 2020|
Type : Article
Mise en ligne par : DIOP Cheikh Abdoul Khadir