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Crystal structure of bis (diisopropylammonium) cis-diiodidobis (oxolato-?2O1, O2) stannate (IV)

In the title compound, (iPr2NH2)2[SnI2(C2O4)2], which was prepared by reacting (iPr2NH2+)2•C2O42? with SnI4 in a 2:1 molar ratio in a mixed ethanol–acetonitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a cis configuration. In the crystal, the cations are linked to the anions by N—H?O and bifurcated N—H?(O,O) hydrogen bonds, generating [10-1] chains.


Auteur(s) : Bougar Sarr, Cheikh Abdoul Khadir Diop, Mamadou Sidibé, Yoann Rousselin
Pages : 502-504
Année de publication : 2018
Revue : Acta Crystallographica Section E: Crystallographic Communications
N° de volume : Vol.74 N°
Type : Article
Mise en ligne par : DIOP Cheikh Abdoul Khadir