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Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-?2O1,O2)stannate(IV)

In the title compound, (iPr2NH2)2[SnI2(C2O4)2], which was prepared by reacting (iPr2NH2+)2 C2O42 with SnI4 in a 2:1 molar ratio in a mixed ethanol– acetonitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a cis configuration. In the crystal, the cations are linked to the anions by N—H O and bifurcated N—H (O,O) hydrogen bonds, generating [101] chains.


Auteur(s) : Bougar Sarr, Cheikh Abdoul Khadir Diop, Mamadou Sidibe ? and Yoann Rousselin
Pages : 502 - 504
Année de publication : 2018
Revue : Acta Crystallographica Section E
N° de volume : E74
Type : Article
Mise en ligne par : SIDIBE Mamadou