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Benzyltriphenylphosphonium dichloridotriphenylstannate(IV)

The crystal structure of the title salt, (C25H22P)[Sn(C6H5)3Cl2] or (PhCH2PPh3)[SnPh3Cl2], consists of [PhCH2PPh3]+ cations and [SnPh3Cl2]  anions in which the SnIVatom is linked to two Cl atoms and three phenyl groups in a trigonal–bipyramidal geometry, with the Cl atoms in trans positions. The cation adopts a tetrahedral geometry. In the crystal, the cations and the anions are connected by C—H  Cl hydrogen bonds, leading to an infinite chain propagating along the c direction.


Auteur(s) : Bocar Traore, Mouhamadou Sembene Boye, Mamadou Sidibe, Libasse Diop and Philippe Guionneau
Pages : m42
Année de publication : 2013
Revue : Acta Crystallographica Section E Structure Reports Online
N° de volume : E69
Type : Article
Mise en ligne par : TRAORE Bocar