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Sheets of Tetranuclear Ni(II) [2 × 2] Square Grids Structure with Infinite Orthogonal Two-Dimensional Water–Chlorine Chains

The tetranuclear nickel(II) complex [Ni4(HL)4]Cl4·4H2O {H2L = 1,5-bis[1-(pyridin-2-yl)ethylidene]carbono hydrazone} has been prepared by reaction in methanol of nickel(II) chloride and H2L in 2:1, M:L molar ratio. The single crystal X-ray diffraction analysis revealed a 2 × 2 square grid of tetramer units with the metal ions joined in pairs by the alkoxide oxygen atom in the ?2 mode with octahedral geometry around each nickel ion. The supramolecular structure shows that the tetramer units are linked through edge-to-face (T shape) C–H···? interactions, forming sheets with hydrophobic- (occupied by infinite 2D water–chlorine chains) and hydrophilic- (occupied by chlorine anions) channels. Variable temperature magnetic studies suggest an antiferromagnetic coupling between the adjacent Ni(II) centers with a coupling constant of J = ?6.6 cm–1.

Auteur(s) : Mouhamadou Moustapha-Sow, Ousmane Diouf, Mohamed Gaaye, Abdou Salam-Sall, Goretti Castro, Paulo Pérez-Lourido, Laura Valencia, Andrea Caneschi, and Lo
Pages : 4172?4176
Année de publication : 2013
Revue : Cryst. Growth Des.
N° de volume : 13
Type : Article
Mise en ligne par : SALL Abdou Salam